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Yes, Blah.valueOf("A") will give you Blah.A.

Note that the name must be an exact match, including case: Blah.valueOf("a") and Blah.valueOf("A ") both throw an IllegalArgumentException.

The static methods valueOf() and values() are created at compile time and do not appear in source code. They do appear in Javadoc, though; for example, Dialog.ModalityType shows both methods.

No, the structure you found is how Java handles it (that is, with overloading instead of default parameters).

For constructors, See Effective Java: Programming Language Guide's Item 1 tip (Consider static factory methods instead of constructors) if the overloading is getting complicated. For other methods, renaming some cases or using a parameter object can help. This is when you have enough complexity that differentiating is difficult. A definite case is where you have to differentiate using the order of parameters, not just number and type.